{rfName}
Pr

Indexed in

License and use

Icono OpenAccess

Citations

3

Altmetrics

Analysis of institutional authors

Salaverri NAuthorMartínez-Fernández LAuthorAleman JCorresponding AuthorMarzo LCorresponding Author

Share

May 26, 2024
Publications
>
Article
Sí

Proton-coupled electron transfer ring opening of Cycloalkanols followed by a giese radical addition enabled by an electron donor-acceptor complex

Publicated to:ORGANIC LETTERS. 26 (21): 4542-4547 - 2024-05-22 26(21), DOI: 10.1021/acs.orglett.4c01443

Authors: Carli B; Salaverri N; Martinez-Fernandez L; Goicuría M; Alemán J; Marzo L

Affiliations

Organic Chemistry Department (Módulo 1), Universidad Autónoma de Madrid, Calle Francisco Tomás y Valiente 7, 28049 Madrid, Spain. - Author

Abstract

Herein, we describe the formation of an electron donor-acceptor (EDA) complex between electron-rich cycloalkanols and electron-deficient alkenes that triggers the proton-coupled electron transfer ring opening of strained and unstrained cycloalkanols without the need for an external photocatalyst. This activation generates a remote alkyl radical that undergoes a Giese reaction with the Michael acceptor in an efficient manner. Mechanistic investigations corroborate both the formation of the EDA complex and the consecutive Giese reaction.

Keywords

BiochemistryBiodiversidadeBiotecnologíaChemistry, organicCiências agrárias iCiências biológicas iCiências biológicas iiFarmaciaGeneral medicineInterdisciplinarMateriaisMedicina iMedicina iiOrganic chemistryPhysical and theoretical chemistryQuímica

Quality index

Bibliometric impact. Analysis of the contribution and dissemination channel

The work has been published in the journal ORGANIC LETTERS due to its progression and the good impact it has achieved in recent years, according to the agency WoS (JCR), it has become a reference in its field. In the year of publication of the work, 2024 there are still no calculated indicators, but in 2023, it was in position 4/57, thus managing to position itself as a Q1 (Primer Cuartil), in the category Chemistry, Organic. Notably, the journal is positioned above the 90th percentile.

Impact and social visibility

From the perspective of influence or social adoption, and based on metrics associated with mentions and interactions provided by agencies specializing in calculating the so-called "Alternative or Social Metrics," we can highlight as of 2025-10-13:

  • The use, from an academic perspective evidenced by the Altmetric agency indicator referring to aggregations made by the personal bibliographic manager Mendeley, gives us a total of: 10.
  • The use of this contribution in bookmarks, code forks, additions to favorite lists for recurrent reading, as well as general views, indicates that someone is using the publication as a basis for their current work. This may be a notable indicator of future more formal and academic citations. This claim is supported by the result of the "Capture" indicator, which yields a total of: 10 (PlumX).

With a more dissemination-oriented intent and targeting more general audiences, we can observe other more global scores such as:

  • The Total Score from Altmetric: 8.5.
  • The number of mentions on the social network X (formerly Twitter): 13 (Altmetric).

It is essential to present evidence supporting full alignment with institutional principles and guidelines on Open Science and the Conservation and Dissemination of Intellectual Heritage. A clear example of this is:

  • The work has been submitted to a journal whose editorial policy allows open Open Access publication.
  • Assignment of a Handle/URN as an identifier within the deposit in the Institutional Repository: https://repositorio.uam.es/handle/10486/712921

Leadership analysis of institutional authors

There is a significant leadership presence as some of the institution’s authors appear as the first or last signer, detailed as follows: First Author (Carli B) and Last Author (MARZO PUERTA, LEYRE).

the authors responsible for correspondence tasks have been ALEMAN LARA, JOSE JULIAN and MARZO PUERTA, LEYRE.