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Analysis of institutional authors

Alonso, InesAuthorTortosa, MariolaCorresponding AuthorCid, M BelenCorresponding Author
January 23, 2023
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Article
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Diboron reagents in the deoxygenation of nitrones

Publicated to: ORGANIC & BIOMOLECULAR CHEMISTRY. 21 (4): 807-816 - 2023-01-01 21(4), DOI: 10.1039/d2ob01880b

Authors: Vargas, Emily L.; Franco, Mario; Alonso, Ines; Tortosa, Mariola; Cid, M. Belen;

Affiliations

Univ Autonoma Madrid, Dept Organ Chem, Madrid 28049, Spain - Author
Univ Autonoma Madrid, Inst Adv Res Chem Sci IAdChem, Madrid 28049, Spain - Author

Abstract

B(2)nep(2) efficiently promotes the N-O cleavage of nitrones to form imines in very high yields via a simple, efficient, sustainable, functional group tolerant and scalable protocol. The reaction occurs in the absence of additives through a concerted mechanism. We demonstrated that DMPO and TEMPO, typically used as radical traps, are also deoxygenated by diboron reagents, which demonstrates their limitation as mechanistic probes.

Keywords

AldiminesAmine n-oxidesArylnitronesBondChemoselective deoxygenationEfficientGeneral-methodIminesOne-pot synthesisReduction

Quality index

Bibliometric impact. Analysis of the contribution and dissemination channel

The work has been published in the journal ORGANIC & BIOMOLECULAR CHEMISTRY due to its progression and the good impact it has achieved in recent years, according to the agency WoS (JCR), it has become a reference in its field. In the year of publication of the work, 2023, it was in position 13/58, thus managing to position itself as a Q1 (Primer Cuartil), in the category Chemistry, Organic.

Impact and social visibility

From the perspective of influence or social adoption, and based on metrics associated with mentions and interactions provided by agencies specializing in calculating the so-called "Alternative or Social Metrics," we can highlight as of 2025-12-05:

  • The use, from an academic perspective evidenced by the Altmetric agency indicator referring to aggregations made by the personal bibliographic manager Mendeley, gives us a total of: 2.
  • The use of this contribution in bookmarks, code forks, additions to favorite lists for recurrent reading, as well as general views, indicates that someone is using the publication as a basis for their current work. This may be a notable indicator of future more formal and academic citations. This claim is supported by the result of the "Capture" indicator, which yields a total of: 2 (PlumX).

With a more dissemination-oriented intent and targeting more general audiences, we can observe other more global scores such as:

  • The Total Score from Altmetric: 1.
  • The number of mentions on the social network X (formerly Twitter): 2 (Altmetric).

Leadership analysis of institutional authors

There is a significant leadership presence as some of the institution’s authors appear as the first or last signer, detailed as follows: First Author (Vargas, Emily L) and Last Author (CID DE LA PLATA, MARIA BELEN).

the authors responsible for correspondence tasks have been Tortosa Manzanares, Mariola and CID DE LA PLATA, MARIA BELEN.

Acknowledgements linked to the item

We acknowledge the financial support provided by the European Research Council (ERC-337776) and the Spanish Government (CTQ2016-78779-R, PID2019-107380GB-I00). E. L. Vargas thanks the University of Costa Rica for a PhD scholarship. A generous allocation of computing time at the Centro de Computacion Cientifica of the UAM is also acknowledged.